Mild and Site-Selective Allylation of Enol Carbamates with Allylic Carbonates under Rhodium Catalysis.
نویسندگان
چکیده
The rhodium(III)-catalyzed mild and site-selective C-H allylation of enol carbamates with 4-vinyl-1,3-dioxolan-2-one and allylic carbonates affords allylic alcohols and terminal allylated products, respectively. The assistance of the carbamoyl directing group provides a straightforward preparation of biologically and synthetically important allylated enol carbamates.
منابع مشابه
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 81 6 شماره
صفحات -
تاریخ انتشار 2016